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Same thing, different name. I think Google just wanted to have a name that was more inclusive of different sized business. After all, how many owners of small businesses with only 2 or 3 employees go out looking for “enterprise” software? I suspect not too many. The term “enterprise” makes it sound like Google’s offering is for Fortune 500 companies, not the mom and pop store around the corner. By calling it Google for Work (or Google Apps for Work) instead, it sounds much more accessible to the average person, and not so much like a product that requires an in-house IT department.